HYDROGEN PEROXIDE SOLUTION, 1.5%
1. === Product Identification ===
Synonyms: Hydrogen dioxide SolutionIngredient |
CAS No | Percent | Hazardous |
|---|---|---|---|
| Hydrogen Peroxide | 7722-84-1 | 2 - 4 % | Yes |
| Water | 7732-18-5 | 96 - 98 % | No |
Emergency Overview
--------------------------
WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION.
Potential Health Effects
----------------------------------
Inhalation:
Not expected to be a health hazard under normal conditions.
Ingestion:
Large oral doses may cause irritation and blistering to the mouth, throat, and abdomen. May also cause abdominal pain, vomiting, and diarrhea.
Skin Contact:
No adverse effects expected on intact skin. Contact on burn or open skin may cause stinging pain or irritation.
Eye Contact:
Causes irritation, redness, and pain.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.
Inhalation:
Not expected to require first aid measures.
Ingestion:
Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact:
Not expected to require first aid measures. Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Fire:
Not considered to be a fire hazard. Concentrated hydrogen peroxide (30%) is a strong oxidizer, but this dilute product does not present that hazard.
Explosion:
Not considered to be an explosion hazard. Drying of concentrated hydrogen peroxide on clothing or other combustible materials may cause fire or explosion.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Contain and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Small amounts of residue may be flushed to sewer with plenty of water.
Store in a cool, well-ventilated dark area. Protect from freezing. Isolate from incompatible substances. Protect container from physical damage. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.
8. === Exposure Controls /Personal Protection ===
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
1 ppm (TWA) for hydrogen peroxide
-ACGIH Threshold Limit Value (TLV):
1 ppm (TWA) for hydrogen peroxide, A3: Animal Carcinogen
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices , most recent edition, for details.
Personal Respirators (NIOSH Approved):
Not expected to require personal respirator usage. If the exposure limit is exceeded and engineering controls are not feasible, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus. Breathing air quality must meet the requirements of the OSHA respiratory protection standard (29CFR1910.134). This substance has unknown warning properties.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
9. === Physical/Chemical Properties ===
Appearance:
Clear, colorless liquid.
Odor:
Odorless.
Solubility:
Complete (100%)
Specific Gravity:
1.01
pH:
No information found.
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
ca. 100C (ca. 212F)
Melting Point:
ca. 0C (ca. 32F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Decomposes to water and oxygen.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Heat, reducing agents, organic materials, dirt, alkalis, rust, and many metals.
Conditions to Avoid:
Light, heat, incompatibles.
For Hydrogen peroxide: No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated as a tumorigen and mutagen.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Hydrogen Peroxide (7722-84-1) No No 3
Water (7732-18-5) No No None
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dilute with water and flush to sewer if local ordinances allow, otherwise, whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Not regulated.
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Hydrogen Peroxide (7722-84-1) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Hydrogen Peroxide (7722-84-1) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Hydrogen Peroxide (7722-84-1) No No No No
Water (7732-18-5) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Hydrogen Peroxide (7722-84-1) No No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: No Fire: Yes Pressure: No
Reactivity: Yes (Mixture / Liquid)
Australian Hazchem Code: 2P
Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 1
Label Hazard Warning:
WARNING! MAY BE HARMFUL IF SWALLOWED. CAUSES EYE IRRITATION.
Label Precautions:
Avoid contact with eyes.
Keep container closed.
Wash thoroughly after handling.
Label First Aid:
In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. If swallowed, give large amounts of water to drink. Never give anything by mouth to an unconscious person. If large amounts were swallowed, get medical advice.
Product Use:
Laboratory Reagent.
High Valley Products, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
HIGH VALLEY PRODUCTS, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, HIGH VALLEY PRODUCTS, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
Revision Date 1/2007