AUTOLIV MIX

1. === Product Identification ===

Emergency Overview
--------------------------
POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG DAMAGE. AFFECTS THE LIVER AND KIDNEYS.

Potential Health Effects
----------------------------------

Inhalation:
Corrosive! Inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory failure, and death.
May result in ulceration and perforation of respiratory tract. When heated, this compound may give off copper fume, which can cause symptoms similar to the common cold, including chills and stuffiness of the head.

Ingestion:
Corrosive! Swallowing may be fatal. Hydrochloric acid can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. Hemorrhagic gastritis, nausea, vomiting, abdominal pain, metallic taste, and diarrhea may occur. Systemic copper poisoning may occur. Symptoms may include capillary damage, headache, cold sweat, weak pulse, kidney and liver damage, central nervous excitation followed by depression, jaundice, convulsions, blood effects, paralysis and coma. Death may occur from shock or renal failure. Fatalities have occurred as a result of ingesting gram quantities of copper sulfate.
Skin Contact:
Corrosive! Can cause redness, pain, and severe skin burns. Concentrated solutions cause deep ulcers and discolor skin.
Eye Contact:
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage.
Chronic Exposure:
Long-term exposure to concentrated vapors may cause erosion of teeth. Prolonged or repeated skin exposure may cause dermatitis. Prolonged or repeated exposure to dusts of copper salts may cause discoloration of the skin or hair, blood and liver damage, ulceration and perforation of the nasal septum, runny nose, metallic taste, and atrophic changes and irritation of the mucous membranes.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, impaired liver, kidney, or pulmonary function, glucose 6-phosphate-dehydrogenase deficiency, or pre-existing Wilson's disease may be more susceptible to the effects of this material.

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Fire:
Extreme heat or contact with metals can release flammable hydrogen gas.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
If involved in a fire, use water spray. Neutralize with soda ash or slaked lime.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Structural firefighter's protective clothing is ineffective for fires involving hydrochloric acid. Stay away from ends of tanks. Cool tanks with water spray until well after fire is out.

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.

Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of direct sunlight and away from heat, water, and incompatible materials. Do not wash out container and use it for other purposes. When diluting, the acid should always be added slowly to water and in small amounts. Never use hot water and never add water to the acid. Water added to acid can cause uncontrolled boiling and splashing. When opening metal containers, use non-sparking tools because of the possibility of hydrogen gas being present. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.

8. === Exposure Controls /Personal Protection ===

Airborne Exposure Limits:
For Hydrochloric acid:
- OSHA Permissible Exposure Limit (PEL):
5 ppm (Ceiling)
- ACGIH Threshold Limit Value (TLV):
2 ppm (Ceiling), A4 Not classifiable as a human carcinogen

For Copper Sulfate:
-OSHA Permissible Exposure Limit (PEL):
1 mg/m3 (TWA) for copper dusts & mists as Cu
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 (TWA) for copper dusts & mists as Cu

Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. === Physical/Chemical Properties ===

Appearance:
Green, fuming liquid.
Odor:
Pungent odor of hydrogen chloride.
Solubility:
Infinite in water with slight evolution of heat.
Density:
Not available
pH:
For HCL solutions: 0.1 (1.0 N), 1.1 (0.1 N), 2.02 (0.01 N)
% Volatiles by volume @ 21C (70F):
100
Boiling Point:
53C (127F) Azeotrope (20.2%) boils at 109C (228F)
Melting Point:
-74C (-101F)
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
190 @ 25C (77F)
Evaporation Rate (BuAc=1):
No information found.

Stability:
Stable under ordinary conditions of use and storage. Containers may burst when heated.
Hazardous Decomposition Products:
When heated to decomposition, emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic and corrosive fumes. Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
A strong mineral acid, concentrated hydrochloric acid is incompatible with many substances and highly reactive with strong bases, metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. Incompatible with materials such as cyanides, sulfides, sulfites, and formaldehyde. substance will ignite hydroxylamine. Solutions are acidic and can react with magnesium to evolve flammable hydrogen gas. May react with acetylene to form dangerous acetylides.
Conditions to Avoid:
Heat, direct sunlight.

Inhalation rat LC50: 3124 ppm/1H; oral rabbit LD50: 900 mg/kg (Hydrochloric acid concentrated); investigated as a tumorigen, mutagen, reproductive effector.

  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Hydrogen Chloride (7647-01-0)           No          No              3
  Water (7732-18-5)                       No          No            None

 Oral rat LD50: 300 mg/kg. Investigated as a tumorigen, mutagen.
--------\Cancer Lists\---------------------------------------------------------NTP Carcinogen---
Ingredient Known Anticipated IARC Category<br>
------------------------------------ ----- ----------- -------------
Cupric Sulfate (7758-98-7) No No None

Environmental Fate:
When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater.
Environmental Toxicity:
This material is expected to be toxic to aquatic life.

Environmental Fate:
Data for anhydrous Copper Sulfate material unless otherwise noted. When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater. When released into water, this material is not expected to biodegrade. When released into water, this material is not expected to evaporate significantly. This material is expected to significantly bioaccumulate. This material has an experimentally-determined bioconcentration factor (BCF) of greater than 100. Bioaccumulation data for copper.
Environmental Toxicity:
This material is expected to be very toxic to aquatic life. The LC50/96-hour values for fish are less than 1 mg/l. The IC50/72-hour values for algae are less than 1 mg/l. Toxicity data for copper.
Cupric Sulfate:
96 Hr LC50 rainbow trout: 0.1 mg/L;
48 Hr LC50 bluegill: 0.6 mg/L;
96 Hr LC50 goldfish: 0.1 mg/L
48 Hr EC50 water flea: 0.024 mg/L

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: CORROSIVE LIQUIDS, N.O.S., (HYDROFHLORIC ACID)
Hazard Class: 8
UN/NA: UN1760
Packing Group: II

  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Hydrogen Chloride (7647-01-0)                     Yes  Yes   Yes      Yes                                      
  Cupric Sulfate (7758-98-7)                        Yes  Yes   Yes      Yes   
  Water (7732-18-5)                                 Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Hydrogen Chloride (7647-01-0)                     Yes   Yes   No     Yes          
  Cupric Sulfate (7758-98-7)                        Yes   Yes   No     Yes  
  Water (7732-18-5)                                 Yes   Yes   No     Yes
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Hydrogen Chloride (7647-01-0)              5000  500*    Yes        No
  Cupric Sulfate (7758-98-7)                 No    No      No    Copper compo  
  Water (7732-18-5)                          No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Hydrogen Chloride (7647-01-0)              5000       No         No        
  Cupric Sulfate (7758-98-7)                 10         No         No   
  Water (7732-18-5)                          No         No         No                                                                
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  Yes
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Mixture / Liquid)

Australian Hazchem Code: 2R
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

Label Hazard Warning:
OISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED. INHALATION MAY CAUSE LUNG DAMAGE. AFFECTS THE LIVER AND KIDNEYS.
Label Precautions:
Do not get in eyes, on skin, or on clothing.
Do not breathe vapor or mist.
Use only with adequate ventilation.
Wash thoroughly after handling.
Store in a tightly closed container.
Remove and wash contaminated clothing promptly.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.

High Valley Products, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

HIGH VALLEY PRODUCTS, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, HIGH VALLEY PRODUCTS, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.